A new catalyst combining copper nanoparticles with a special type of graphene could lead to a greener way of producing ethylene, a key commodity chemical.
PROVIDENCE, R.I. [Brown University] — The world has more carbon dioxide than it needs, and a team of Brown University chemists has come up with a potential way to put some of it to good use. (more…)
Berkeley Lab researchers find new mechanism to explain the birth of cloud droplets, could influence climate models
There is enough known about cloud formation that replicating its mechanism has become a staple of the school science project scene. But a new study by scientists at the U.S. Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab) reveals that much more is going on at the microscopic level of cloud formation than previously thought. (more…)
UD researchers report on new catalyst to convert greenhouse gases into chemicals
A team of researchers at the University of Delaware has developed a highly selective catalyst capable of electrochemically converting carbon dioxide — a greenhouse gas — to carbon monoxide with 92 percent efficiency. The carbon monoxide then can be used to develop useful chemicals.
The researchers recently reported their findings in Nature Communications. (more…)
Many of the metals needed to feed the surging global demand for high-tech products, from smart phones to solar panels, cannot be replaced, leaving some markets vulnerable if resources become scarce, according to a new Yale study.
In a comprehensive analysis, a team of researchers from the Yale School of Forestry & Environmental Studies (F&ES) evaluated how all 62 metals or metalloids on the periodic table of elements are used in consumer products, and the extent to which each of those metals could be replaced if reserves dwindle or supplies become unreliable. (more…)
Berkeley Lab Researchers Develop New Technique for Heterogenizing Homogenous Nano Catalysts
Catalysts are substances that speed up the rates of chemical reactions without themselves being chemically changed. Industrial catalysts come in two main types – heterogeneous, in which the catalyst is in a different phase from the reactants; and homogeneous, in which catalyst and the reactants are in the same phase. Heterogeneous catalysts are valued for their sustainability because they can be recycled. Homogeneous catalysts are valued for their product selectivity as their properties can be easily tuned through relatively simple chemistry.
Researchers with the U.S. Department of Energy (DOE)’s Lawrence Berkeley National Laboratory (Berkeley Lab) have combined the best properties of both types of industrial catalysts by encapsulating nanoclusters of a metallic heterogeneous catalyst within the branched arms of the molecules known as dendrimers. (more…)
‘Greener’ and more engaging experiments draw students in
As a college student, Michelle Driessen had an all-too-typical experience.
“I hated general chemistry,” she says. “I thought it was terribly boring.”
She had plenty of company. Experiments were all laid out in advance, and the goal seemed to be to get to a predetermined result without blowing up the glassware.
In the old days, “very few students appreciated the point of most general chemistry labs,” adds Driessen. “With cookbook chemistry, you couldn’t have anything go wrong or deviate [from what’s supposed to happen], but I find those things to be the most interesting part of science.” (more…)
Chemists at Brown University have created a triple-headed metallic nanoparticle that reportedly performs better and lasts longer than any other nanoparticle catalyst studied in fuel-cell reactions. The key is the addition of gold: It yields a more uniform crystal structure while removing carbon monoxide from the reaction. Results published in the Journal of the American Chemical Society.
PROVIDENCE, R.I. [Brown University] — Advances in fuel-cell technology have been stymied by the inadequacy of metals studied as catalysts. The drawback to platinum, other than cost, is that it absorbs carbon monoxide in reactions involving fuel cells powered by organic materials like formic acid. A more recently tested metal, palladium, breaks down over time. (more…)
A technique for creating a new molecule that structurally and chemically replicates the active part of the widely used industrial catalyst molybdenite has been developed by researchers with the U.S. Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab). This technique holds promise for the creation of catalytic materials that can serve as effective low-cost alternatives to platinum for generating hydrogen gas from water that is acidic.
Christopher Chang and Jeffrey Long, chemists who hold joint appointments with Berkeley Lab and the University of California (UC) Berkeley, led a research team that synthesized a molecule to mimic the triangle-shaped molybdenum disulfide units along the edges of molybdenite crystals, which is where almost all of the catalytic activity takes place. Since the bulk of molybdenite crystalline material is relatively inert from a catalytic standpoint, molecular analogs of the catalytically active edge sites could be used to make new materials that are much more efficient and cost-effective catalysts. (more…)
