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Nanoscale Coatings Improve Stability and Efficiency of Devices for Renewable Fuel Generation

By Guest PostDecember 7, 2013Environment, Scienceaaron k vannucci, acidic, ald, atomic layer deposition, berc kalanyan, carbon dioxide, carbon neutral fuels, chemical pathway, device, efficiency, Environment, gregory parsons, hydrocarbon fuel, hydrogen, klondike bar, leila alibabaei, low ph, mark losego, molecular catalysts, molecular photoelectrochemical cell, nanoscale coatings, north Carolina, oxygen, ph, renewable fuel generation, solar water splitting, stability, state university, ultra thin layer, water oxidation, water splitting devices

Splitting water into its components, two parts hydrogen and one part oxygen, is an important first step in achieving carbon-neutral fuels to power our transportation infrastructure – including automobiles and planes.

Now, North Carolina State University researchers and colleagues from the University of North Carolina at Chapel Hill have shown that a specialized coating technique can make certain water-splitting devices more stable and more efficient. Their results are published online in two separate papers in the Proceedings of the National Academy of Sciences. (more…)

Acidifying oceans could spell trouble for squid

By Guest PostJune 25, 2013Environmentacidic, acidic oceans, acidifying oceans, anne cohen, atlantic longfin squid, atmosphere, biologist, calcium carbonate, carbon dioxide, carbonate crystals, carbonic acid, coastal economies, daniel mccorkle, economic loss, egg capsules, loligo pealeii, max kaplan, ocean environment, parameters, ph of water, seawater, st andrews, statoliths, t aran mooney, tom kleindinst, trouble for squid, uk, university, vineyard sound, vineyard sound seawater, whoi

New study reveals more acid seas could alter early development of Atlantic longfin squid

Acidifying oceans could dramatically impact the world’s squid species, according to a new study led by Woods Hole Oceanographic Institution (WHOI) researchers and just published online in the journal PLOS ONE. Because squid are both ecologically and commercially important, that impact may have far-reaching effects on the ocean environment and coastal economies, the researchers report.

“Squid are at the center of the ocean ecosystem—nearly all animals are eating or eaten by squid,” says WHOI biologist T. Aran Mooney, a co-author of the study. “So if anything happens to these guys, it has repercussions down the food chain and up the food chain.” (more…)

New Study Reveals How Sensitive U.S. East Coast Regions May Be to Ocean Acidification

By Guest PostApril 1, 2013Environmentacidic, acidic environment, bicarbonate, buffer capacity, carbon dioxide, carbon in ocean, carbonate, carbonic acid, changes in acidity, chemical survey, CO2, co2 levels, coastal ocean acidification, continental scale, coral, corpus christi, dic, dissolved co2, dissolved inorganic carbon, florida strait, galveston, georgia, glaciers, gulf of maine, gulf of mexico, influx of co2, labrador sea, melting sea ice, middle atlantic bight, Mississippi, ocean acidification, offshore, oysters, pteropods, rik wanninkhof, robert h byrne, ronald h brown, snails, texas, total alkalinity, tsung hung peng, university of georgia, us east coast, water ph, whoi, wie jen huang, wie jun cai, xinping hu, zhaohui aleck wang

A continental-scale chemical survey in the waters of the eastern U.S. and Gulf of Mexico is helping researchers determine how distinct bodies of water will resist changes in acidity. The study, which measures varying levels of carbon dioxide (CO₂) and other forms of carbon in the ocean, was conducted by scientists from 11 institutions across the U.S. and was published in the journal Limnology and Oceanography.

“Before now, we haven’t had a very clear picture of acidification status on the east coast of the U.S.,” says Zhaohui ‘Aleck’ Wang, the study’s lead author and a chemical oceanographer at Woods Hole Oceanographic Institution (WHOI). “It’s important that we start to understand it, because increase in ocean acidity could deeply affect marine life along the coast and has important implications for people who rely on aquaculture and fisheries both commercially and recreationally.” (more…)

Acid Rain

By Guest PostMay 4, 2012Environmentacid rain, acidic, acidity, air, basic, canopy, cape henlopen, carbonic acid, clean air act, concentration, copper, delaware rain, ecosystem, joseph scudlark, lake sediments, lead, lewes, marine studies, mercury, monitoring, nitric, organism, ph, pollutant, precipitation, rainwater, state park, sulfuric, thomas church, trace metal, zinc

UD’s long-term monitoring shows 60 percent reduction in acidity of Delaware rain

Several decades ago, precipitation in Delaware was among the most acidic in the country. Pollutants in the air reacted with rainwater to sprinkle sulfuric, nitric and carbonic acids onto the ground below, affecting crops and ecosystems statewide.

The scientific consensus is that pollution controls enacted through the Clean Air Act Amendments in the 1990s and other measures have helped decrease the acidity of rain by approximately 60 percent to less harmful levels, as reflected in data gathered nationwide and by UD researchers in Lewes, Del., as part of a longstanding study. (more…)

Hydrogen from Acidic Water: Berkeley Lab Researchers Develop a Potential Low Cost Alternative to Platinum for Splitting Water

By Guest PostFebruary 12, 2012Scienceacidic, acidic water, artificial photosynthesis, berkeley lab, catalyst, catalytic hydrogen generation, christopher chang, elizabeth montalvo, emission, hemamala karunadasa, hhmi, hydrogen gas, jeffrey long, low cost alternatives, marcin majda, microdomains, molecule, molybdenite, molybdenite crystals, molybdenum disulfide, natural gas, pentapyridyl ligand, petroleum, photocatalytic systems, platinum, py5me2, reduction, sulfur, sulfur dioxide, water, yujie sun

A technique for creating a new molecule that structurally and chemically replicates the active part of the widely used industrial catalyst molybdenite has been developed by researchers with the U.S. Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab). This technique holds promise for the creation of catalytic materials that can serve as effective low-cost alternatives to platinum for generating hydrogen gas from water that is acidic.

Christopher Chang and Jeffrey Long, chemists who hold joint appointments with Berkeley Lab and the University of California (UC) Berkeley, led a research team that synthesized a molecule to mimic the triangle-shaped molybdenum disulfide units along the edges of molybdenite crystals, which is where almost all of the catalytic activity takes place. Since the bulk of molybdenite crystalline material is relatively inert from a catalytic standpoint, molecular analogs of the catalytically active edge sites could be used to make new materials that are much more efficient and cost-effective catalysts. (more…)

Listen Up: Ocean Acidification Poses Little Threat to Whales’ Hearing

By Guest PostOctober 13, 2010Environmentabsorption, acidic, animals, atmospheric carbon dioxide, boric acid, CO2, decibel, hearing, ilya udovydchenkov, ivan lima, mathematical models, noise levels, ocean, ocean acidification, scott doney, seawater, sound propagation, sound waves, tim duda, whales, whoi, woods hole oceanographic institution

Contrary to some previous, highly publicized, reports, ocean acidification is not likely to worsen the hearing of whales and other animals, according to a Woods Hole Oceanographic Institution (WHOI) scientist who studies sound propagation in the ocean. (more…)

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