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Artificial Forest for Solar Water-Splitting

Berkeley Lab Researchers Report First Fully Integrated Artificial Photosynthesis Nanosystem

In the wake of the sobering news that atmospheric carbon dioxide is now at its highest level in at least three million years, an important advance in the race to develop carbon-neutral renewable energy sources has been achieved. Scientists with the U.S. Department of Energy (DOE)’s Lawrence Berkeley National Laboratory (Berkeley Lab) have reported the first fully integrated nanosystem for artificial photosynthesis. While “artificial leaf” is the popular term for such a system, the key to this success was an “artificial forest.”

“Similar to the chloroplasts in green plants that carry out photosynthesis, our artificial photosynthetic system is composed of two semiconductor light absorbers, an interfacial layer for charge transport, and spatially separated co-catalysts,” says Peidong Yang, a chemist with Berkeley Lab’s Materials Sciences Division, who led this research. “To facilitate solar water- splitting in our system, we synthesized tree-like nanowire heterostructures, consisting of silicon trunks and titanium oxide branches. Visually, arrays of these nanostructures very much resemble an artificial forest.” (more…)

A New Way of Looking at Photosystem II

By Guest PostJune 14, 2012Sciencealgae, angstroms, bacteria, berkeley lab, carbon dioxide, catalytic cycle, critical formation, cryogenic freezing, electrochemical energy, electrons, femtosecond timescale, femtosecond x ray pulses, green, green plants, hydrogen atom, hydrogen ions, jan kern, junko yano, knowledge, lcls, microcrystals, nicholas sauter, oxidation states, oxygen molecules, paul adams, photooxidation, photosynthesis, photosystem ii, protein crystallography, proteins, protons, renewable energy, resolution, slac, solar energy, synchrotron radiation, terabytes of data, uwe bergmann, vittal yachandra, water, xray diffraction, xrays

Berkeley Lab and SLAC Researchers Study Key Protein Complex Crucial to Photosynthesis

Future prospects for clean, green, renewable energy may hinge upon our ability to mimic and improve upon photosynthesis – the process by which green plants, algae and some bacteria convert solar energy into electrochemical energy. An artificial version of photosynthesis, for example, could use sunlight to produce liquid fuels from nothing more than carbon dioxide and water. First, however, scientists need a better understanding of how a large complex of proteins, called photosystem II, is able to split water molecules into oxygen, electrons and hydrogen ions (protons). A new road to reaching this understanding has now been opened by an international team of researchers, led by scientists at the U.S. Department of Energy (DOE)’s Lawrence Berkeley National Laboratory (Berkeley Lab) and SLAC National Accelerator Laboratory.

Using ultrafast, intensely bright pulses of X-rays from SLAC’s Linac Coherent Light Source (LCLS), the research team produced the first ever images at room temperature of microcrystals of the photosystem II complex. Previous imaging studies, using X-rays generated via synchrotron radiation sources, required cryogenic freezing, which alters the samples. Also, to catalyze its reactions, photosystem II relies upon an enzyme that contains a manganese-calcium cluster that is highly sensitive to radiation. With the high-intensity femtosecond X-ray pulses of the LCLS, the research team was able to record intact images of these clusters before the radiation destroyed them. (more…)

Tag Archives: oxygen molecules

Artificial Forest for Solar Water-Splitting

A New Way of Looking at Photosystem II